Kim, Kyung WanDepartment of Physics, University of Fribourg, Switzerland - School of Physics and Research Center for Oxide Electronics, Seoul National University, Korea
Gu, G. D.Department of Condensed Matter Physics and Materials Science, Brookhaven National Laboratory, Upton, New York, USA
24.02.2009
Published in:
Physical Review B. - 2009, vol. 79, no. 8, p. 085121
English
We investigated excitation spectra of the one-dimensional chain compound Sr₂CuO₃. The small peak at 2.3 eV in the loss function turned out to correspond to the strong charge-transfer transition at 1.8 eV in conductivity. It has the excitonic character expected in one-dimensional extended Hubbard model of the transition from the lower Hubbard band to the Zhang-Rice singlet state. The strongest peak at 2.7 eV in the loss function is attributed to the continuum excitation of the excitonic charge-transfer transition. The spectral weight sum rule is satisfied within these transitions.