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Threading salen-type Cu- and Ni-complexes into one-dimensional coordination polymers: solution versus solid state and the size effect of the alkali metal ion

  • Finelli, Alba Department of Chemistry and, University of Fribourg, Switzerland
  • Hérault, Nelly Department of Chemistry and, University of Fribourg, Switzerland
  • Crochet, Aurélien FriMat, Department of Chemistry, University of Fribourg, Switzerland
  • Fromm, Katharina M. Department of Chemistry and, University of Fribourg, Switzerland
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    07.02.2018
Published in:
  • Crystal Growth & Design. - 2018, vol. 18, no. 2, p. 1215–1226
English Compartmentalization of metal ions is crucial in biology as well as in materials science. For the synthesis of single source precursors, the preorganization of different metal ions is of particular interest for the low-temperature generation of mixed metal oxides. On the basis of a potentially Ω-shaped salen-type ligand providing an N2O2 as well as an O2O2 coordination site, mixed metal coordination compounds with Cu(II) or Ni(II) and alkali metal ions have been studied for their structural and optical properties. UV–vis and 1H NMR titrations show that the obtained compounds adopt partially different structures in solution compared to the solid state. In the latter case, the coordination geometry is mainly governed by the size of the alkali metal ion as well as the transition metal ion used.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/306966
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