Journal article

+ 1 other files

Tandem ring‐opening–ring‐closing metathesis for functional metathesis catalysts

Show more…
    26.09.2016
Published in:
  • Angewandte Chemie International Edition. - 2016, vol. 55, no. 40, p. 12343–12346
English Use of a tandem ring-opening–ring-closing metathesis (RORCM) strategy for the synthesis of functional metathesis catalysts is reported. Ring opening of 7-substituted norbornenes and subsequent ring-closing metathesis forming a thermodynamically stable 6-membered ring lead to a very efficient synthesis of new catalysts from commercially available Grubbs’ catalysts. Hydroxy functionalized Grubbs’ first- as well as third-generation catalysts have been synthesized. Mechanistic studies have been performed to elucidate the order of attack of the olefinic bonds. This strategy was also used to synthesize the ruthenium methylidene complex.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/305339
Other files

Statistics

Document views: 9 File downloads:
  • kil_tro.pdf: 1
  • kil_tro_sm.pdf: 0