Journal article

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Controlled tautomerism – switching caused by an ‘underground’ anionic effect

  • Antonov, Liudmil Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Deneva, Vera Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Kurteva, Vanya Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Nedeltcheva, Daniela Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Crochet, Aurélien Chemistry Department, University of Fribourg, Switzerland
  • Fromm, Katharina M. Chemistry Department, University of Fribourg, Switzerland
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    11.11.2013
Published in:
  • RSC Advances. - 2013, vol. 3, no. 47, p. 25410–25416
English In a previous communication, we demonstrated a conceptual idea for a tautomeric switching system based on implementation of a flexible piperidine unit in 4- (phenyldiazenyl)naphthalen-1-ol (1). The results showed that a directed shift in the position of the tautomeric equilibrium can be achieved through protonation/deprotonation in a number of solvents. However, the effect of the counter ... Show more…
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/303517
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