Singlet-Oxygen-Induced Rearrangement of Furan Derivatives
- Charbonnet, Nicolas Department of Chemistry, University of Fribourg, Switzerland
- Riguet, Emmanuel Department of Chemistry, University of Fribourg, Switzerland
- Bochet, Christian G. Department of Chemistry, University of Fribourg, Switzerland
-
2011
Published in:
- Synlett. - 2012, vol. 15, p. 2231-2233
English
Upon exposure to singlet oxygen and dimethylsulfide, the addition products between 3-furaldehydes and Grignard reagents undergo an oxidative rearrangement to give 2-substituted 3-furaldehydes, in yields ranging from 26-83%. N-Aryl- and N-tosylpyrroles were similarly obtained if the corresponding nitrogen-containing precursors were used instead, in equally attractive yields (64-92%).
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
-
- RERO DOC 27949
- DOI 10.1055/s-0030-1261204
- Persistent URL
- https://folia.unifr.ch/unifr/documents/302343
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