Self-assembly and alignment of semiconductor nanoparticles on cellulose nanocrystals
Padalkar, SonalSchool of Materials Engineering, Purdue University, West Lafayette, USA - Birck Nanotechnology Center, Purdue University, West Lafayette, USA
Capadona, Jeff R.Rehabilitation Research and Development, Louis Stokes Cleveland DVA Medical Center, Cleveland, USA - Department of Biomedical Engineering, Case Western Reserve University, Cleveland, USA - Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, USA
Rowan, Stuart J.Department of Biomedical Engineering, Case Western Reserve University, Cleveland, USA - Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, USA - Department of Chemistry, Case Western Reserve University, Cleveland, USA
Weder, ChristophDepartment of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, USA - Department of Chemistry, Case Western Reserve University, Cleveland, USA - Adolphe Merkle Institute and Fribourg Center for Nanomaterials, University of Fribourg, Switzerland
Moon, Robert J.School of Materials Engineering, Purdue University, West Lafayette, USA - Birck Nanotechnology Center, Purdue University, West Lafayette, USA - US Forest Service, Forest Products Laboratory, Madison, USA
Stanciu, Lia A.School of Materials Engineering, Purdue University, West Lafayette, USA - Birck Nanotechnology Center, Purdue University, West Lafayette, USA
Journal of Materials Science. - 2011, vol. 46, no. 17, p. 5672-5679
English
The synthesis of cadmium sulfide (CdS), zinc sulfide (ZnS), and lead sulfide (PbS) nanoparticle chains on cellulose nanocrystal (CNC) templates can be accomplished by the reaction of the precursor salts. The use of a cationic surfactant, cetyltrimethylammonium bromide (CTAB), was critical for the synthesis of well-defined semiconductor nanoparticle chains on the surface of the CNCs. The semiconductor nanoparticle particle size and packing density on CNC surface could be controlled by the variation of the precursor concentration and the pH of the salt solution.