Journal article
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Polymorph of dibenzo-24-crown-8 and its mercury complex
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Crochet, Aurélien
Department of Chemistry, University of Fribourg, Switzerland
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Kottelat, Emmanuel
Department of Chemistry, University of Fribourg, Switzerland
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Fleury, Antoine
Departement of Chemisty, University of Basel, Switzerland
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Neuburger, Markus
Departement of Chemisty, University of Basel, Switzerland
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Fromm, Katharina M.
Department of Chemistry, University of Fribourg, Switzerland
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Published in:
- Zeitschrift für anorganische und allgemeine Chemie. - 2011, vol. 637, no. 6, p. 672–675
English
Dibenzo-24-crown-8 is studied herein as a flexible ligand able to adopt different conformations, as well as for the complexation of mercury. The recrystallization of dibenzo-24-crown-8 (DB24C8) from dry THF gives a new polymorphic structure of this ligand. This new structure is described and compared to the literature compound. Additionally, coordination of this ligand to mercury iodide HgI₂ is studied.
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Faculty
- Faculté des sciences et de médecine
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Department
- Département de Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/302033
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