Polymorph of dibenzo-24-crown-8 and its mercury complex
- Crochet, Aurélien Department of Chemistry, University of Fribourg, Switzerland
- Kottelat, Emmanuel Department of Chemistry, University of Fribourg, Switzerland
- Fleury, Antoine Departement of Chemisty, University of Basel, Switzerland
- Neuburger, Markus Departement of Chemisty, University of Basel, Switzerland
- Fromm, Katharina M. Department of Chemistry, University of Fribourg, Switzerland
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13.04.2011
Published in:
- Zeitschrift für anorganische und allgemeine Chemie. - 2011, vol. 637, no. 6, p. 672–675
English
Dibenzo-24-crown-8 is studied herein as a flexible ligand able to adopt different conformations, as well as for the complexation of mercury. The recrystallization of dibenzo-24-crown-8 (DB24C8) from dry THF gives a new polymorphic structure of this ligand. This new structure is described and compared to the literature compound. Additionally, coordination of this ligand to mercury iodide HgI₂ is studied.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 25004
- DOI 10.1002/zaac.201100065
- Persistent URL
- https://folia.unifr.ch/unifr/documents/302033
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