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Polyoxometalate-based N-heterocyclic carbene (nhc) complexes for palladium-mediated C-C coupling and chloroaryl dehalogenation catalysis

  • Berardi, Serena ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
  • Carraro, Mauro ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
  • Iglesias, Manuel Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
  • Sartorel, Andrea ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
  • Scorrano, Gianfranco ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
  • Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
  • Bonchio, Marcella ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
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    14.09.2010
Published in:
  • Chemistry, A European Journal. - 2010, vol. 16, no. 35, p. 10662–10666
English Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C cross-coupling and aromatic dehalogenation reactions under MW-assisted protocols
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/301792
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