Polyoxometalate-based N-heterocyclic carbene (nhc) complexes for palladium-mediated C-C coupling and chloroaryl dehalogenation catalysis
- Berardi, Serena ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
- Carraro, Mauro ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
- Iglesias, Manuel Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
- Sartorel, Andrea ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
- Scorrano, Gianfranco ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
- Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
- Bonchio, Marcella ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
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14.09.2010
Published in:
- Chemistry, A European Journal. - 2010, vol. 16, no. 35, p. 10662–10666
English
Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C cross-coupling and aromatic dehalogenation reactions under MW-assisted protocols
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 21082
- DOI 10.1002/chem.201001009
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301792
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