Polyoxometalate-based N-heterocyclic carbene (nhc) complexes for palladium-mediated C-C coupling and chloroaryl dehalogenation catalysis

Berardi, Serena; Carraro, Mauro; Iglesias, Manuel; Sartorel, Andrea; Scorrano, Gianfranco; Albrecht, Martin; Bonchio, Marcella

doi:10.1002/chem.201001009

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Polyoxometalate-based N-heterocyclic carbene (nhc) complexes for palladium-mediated C-C coupling and chloroaryl dehalogenation catalysis

Berardi, Serena ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
Carraro, Mauro ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
Iglesias, Manuel Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
Sartorel, Andrea ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
Scorrano, Gianfranco ITM-CNR and Department of Chemical Sciences, University of Padova, Italy
Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
Bonchio, Marcella ITM-CNR and Department of Chemical Sciences, University of Padova, Italy

14.09.2010

Published in:

Chemistry, A European Journal. - 2010, vol. 16, no. 35, p. 10662–10666

English Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C cross-coupling and aromatic dehalogenation reactions under MW-assisted protocols

Faculty

Faculté des sciences et de médecine

Department

Département de Chimie

Language