Berardi, Serena Carraro, Mauro Iglesias, Manuel Sartorel, Andrea Scorrano, Gianfranco Albrecht, Martin Bonchio, Marcella 2010-09-14 Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C cross-coupling and aromatic dehalogenation reactions under MW-assisted protocols application/pdf https://folia.unifr.ch/global/documents/301792 https://folia.unifr.ch/documents/301792/files/igl_pbc.pdf https://folia.unifr.ch/documents/301792/files/igl_pbc_sm.pdf eng info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201001009 info:eu-repo/semantics/openAccess License undefined Chemistry, A European Journal. - 2010, vol. 16, no. 35, p. 10662–10666 carbenes homogeneous catalysis palladium polyoxometalates info:eu-repo/classification/udc/54 Polyoxometalate-based N-heterocyclic carbene (nhc) complexes for palladium-mediated C-C coupling and chloroaryl dehalogenation catalysis http://purl.org/coar/resource_type/c_6501