Journal article

Polyether adducts of d-block metal compounds as starting materials for new cluster compounds

    26.04.2010
Published in:
  • Zeitschrift für anorganische und allgemeine Chemie. - 2010, vol. 636, no. 8, p. 1484–1496
English New crystalline cobalt, nickel, zinc, and mercury halide adducts with polyethers as ligands have been isolated, characterized, and identified as [Co(μ-Cl)₂CoCl₂(glyme)₂] (glyme = 1,2-dimethoxyethane), cis-[CoI₂(H₂O)₂(glyme)₂]²⁺[CoI₄]²⁻, [NiI₂(glyme)₂], [ZnI₂(glyme)], [HgCl₂(glyme)], [CoI₂(diglyme)] (diglyme = bis(2-methoxyethyl)ether), [ZnI₂(diglyme)], [HgI₂(diglyme)], [CoCl(μ-Cl)(diglyme)]₂, [NiI(μ-I)(diglyme)]₂, [Co(μ-Cl)(triglyme)]₂²⁺[CoCl₂(μ-Cl)]₂²⁻, and cis-[(NiI₂)(triglyme)]n. These compounds were obtained from the metal halide salts in solution of glyme or diglyme, and some of them show unusual coordination numbers and arrangements
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/301669
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