Polyether adducts of d-block metal compounds as starting materials for new cluster compounds
- Crochet, Aurélien University of Fribourg, Department of Chemistry, Fribourg
- Fromm, Katharina M. University of Fribourg, Department of Chemistry, Fribourg
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26.04.2010
Published in:
- Zeitschrift für anorganische und allgemeine Chemie. - 2010, vol. 636, no. 8, p. 1484–1496
English
New crystalline cobalt, nickel, zinc, and mercury halide adducts with polyethers as ligands have been isolated, characterized, and identified as [Co(μ-Cl)₂CoCl₂(glyme)₂] (glyme = 1,2-dimethoxyethane), cis-[CoI₂(H₂O)₂(glyme)₂]²⁺[CoI₄]²⁻, [NiI₂(glyme)₂], [ZnI₂(glyme)], [HgCl₂(glyme)], [CoI₂(diglyme)] (diglyme = bis(2-methoxyethyl)ether), [ZnI₂(diglyme)], [HgI₂(diglyme)], [CoCl(μ-Cl)(diglyme)]₂, [NiI(μ-I)(diglyme)]₂, [Co(μ-Cl)(triglyme)]₂²⁺[CoCl₂(μ-Cl)]₂²⁻, and cis-[(NiI₂)(triglyme)]n. These compounds were obtained from the metal halide salts in solution of glyme or diglyme, and some of them show unusual coordination numbers and arrangements
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 20544
- DOI 10.1002/zaac.201000022
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301669
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