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Inducing spin crossover in amphiphilic iron(III) complexes

  • Martinho, Paulo N. School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
  • Harding, Charles J. Department of Chemistry, The Open University Walton Hall, Milton Keynes, United Kingdom
  • Müller-Bunz, Helge School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
  • Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland
  • Morgan, Grace G. School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
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    05.01.2010
Published in:
  • European Journal of Inorganic Chemistry. - 2010, no. 5, p. 675-679
English Thermal spin crossover (SCO) was induced in a high-spin FeIII complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C₆ alkylation and full transition upon lengthening to C₁₂. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/301530
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