Journal article
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Inducing spin crossover in amphiphilic iron(III) complexes
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Martinho, Paulo N.
School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
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Harding, Charles J.
Department of Chemistry, The Open University Walton Hall, Milton Keynes, United Kingdom
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Müller-Bunz, Helge
School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
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Albrecht, Martin
Department of Chemistry, University of Fribourg, Switzerland
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Morgan, Grace G.
School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
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Published in:
- European Journal of Inorganic Chemistry. - 2010, no. 5, p. 675-679
English
Thermal spin crossover (SCO) was induced in a high-spin FeIII complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C₆ alkylation and full transition upon lengthening to C₁₂. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
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Faculty
- Faculté des sciences et de médecine
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Department
- Département de Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/301530
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