Inducing spin crossover in amphiphilic iron(III) complexes
- Martinho, Paulo N. School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
- Harding, Charles J. Department of Chemistry, The Open University Walton Hall, Milton Keynes, United Kingdom
- Müller-Bunz, Helge School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
- Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland
- Morgan, Grace G. School of Chemistry & Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin Belfield, Dublin, Ireland
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05.01.2010
Published in:
- European Journal of Inorganic Chemistry. - 2010, no. 5, p. 675-679
English
Thermal spin crossover (SCO) was induced in a high-spin FeIII complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C₆ alkylation and full transition upon lengthening to C₁₂. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 17249
- DOI 10.1002/ejic.200901183
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301530
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