Dissociative electron attachment and electron energy-loss spectra of phenyl azide
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Živanov, Svetlana
Department of Chemistry, University of Fribourg, Switzerland
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Ibanescu, Bogdan C.
Department of Chemistry, University of Fribourg, Switzerland
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Paech, M.
Department of Chemistry, University of Fribourg, Switzerland - Leibniz Universität Hannover, Institut für Theoretische Physik, Hannover, Germany
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Poffet, Martine
Department of Chemistry, University of Fribourg, Switzerland
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Baettig, Pio
Department of Chemistry, University of Fribourg, Switzerland
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Sergenton, A.-C.
Department of Chemistry, University of Fribourg, Switzerland
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Grimme, S.
Organisch-Chemisches Institut der Universität Münster, Germany
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Allan, Michael
Department of Chemistry, University of Fribourg, Switzerland
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Published in:
- Journal of Physics B: Atomic, Molecular and Optical Physics. - 2007, vol. 40, no. 1, p. 101-109
English
Electron-induced chemistry—dissociative electron attachment (DEA)—was studied for phenyl azide. The major fragment corresponded to the loss of N₂ and formation of the phenylnitrene anion. This process has an onset already at zero kinetic energy of the incident electron and is interpreted as proceeding via the A″π* electronic ground state of the phenyl azide anion. Other fragments, N₃⁻ and CN⁻,... Show more…
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Faculty
- Faculté des sciences
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Department
- Chimie
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Language
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Classification
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Physics
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/300258