Dissociative electron attachment and electron energy-loss spectra of phenyl azide
- Živanov, Svetlana Department of Chemistry, University of Fribourg, Switzerland
- Ibănescu, Bogdan C. Department of Chemistry, University of Fribourg, Switzerland
- Paech, M. Department of Chemistry, University of Fribourg, Switzerland - Leibniz Universität Hannover, Institut für Theoretische Physik, Hannover, Germany
- Poffet, Martine Department of Chemistry, University of Fribourg, Switzerland
- Baettig, Pio Department of Chemistry, University of Fribourg, Switzerland
- Sergenton, A.-C. Department of Chemistry, University of Fribourg, Switzerland
- Grimme, S. Organisch-Chemisches Institut der Universität Münster, Germany
- Allan, Michael Department of Chemistry, University of Fribourg, Switzerland
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19.12.2006
Published in:
- Journal of Physics B: Atomic, Molecular and Optical Physics. - 2007, vol. 40, no. 1, p. 101-109
English
Electron-induced chemistry—dissociative electron attachment (DEA)—was studied for phenyl azide. The major fragment corresponded to the loss of N₂ and formation of the phenylnitrene anion. This process has an onset already at zero kinetic energy of the incident electron and is interpreted as proceeding via the A″π* electronic ground state of the phenyl azide anion. Other fragments, N₃⁻ and CN⁻,... Show more…
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Physics
- License
- License undefined
- Identifiers
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- RERO DOC 6671
- DOI 10.1088/0953-4075/40/1/009
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300258