Journal article

Dissociative electron attachment and electron energy-loss spectra of phenyl azide

  • Živanov, Svetlana Department of Chemistry, University of Fribourg, Switzerland
  • Ibanescu, Bogdan C. Department of Chemistry, University of Fribourg, Switzerland
  • Paech, M. Department of Chemistry, University of Fribourg, Switzerland - Leibniz Universität Hannover, Institut für Theoretische Physik, Hannover, Germany
  • Poffet, Martine Department of Chemistry, University of Fribourg, Switzerland
  • Baettig, Pio Department of Chemistry, University of Fribourg, Switzerland
  • Sergenton, A.-C. Department of Chemistry, University of Fribourg, Switzerland
  • Grimme, S. Organisch-Chemisches Institut der Universität Münster, Germany
  • Allan, Michael Department of Chemistry, University of Fribourg, Switzerland
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    19.12.2006
Published in:
  • Journal of Physics B: Atomic, Molecular and Optical Physics. - 2007, vol. 40, no. 1, p. 101-109
English Electron-induced chemistry—dissociative electron attachment (DEA)—was studied for phenyl azide. The major fragment corresponded to the loss of N₂ and formation of the phenylnitrene anion. This process has an onset already at zero kinetic energy of the incident electron and is interpreted as proceeding via the A″π* electronic ground state of the phenyl azide anion. Other fragments, N₃⁻ and CN⁻,... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Physics
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/300258