Generation of alkoxyl radicals and their applications for ß-scission reactions in bridged bicyclic systems
- Giraud, Anne
- Renaud, Philippe (degree supervisor)
- Cossy, Janine (degree supervisor)
-
16.10.2000
138 p
Thèse de doctorat: Université de Fribourg, 2000
English
French
Due to their peculiar reactivity, alkoxyl radicals have unique characteristic properties, which make them powerful tools in modern organic chemistry. Among their typical transformations, β-scission reactions have retained our interest because of their potential in converting stereoselectively bridged bicyclic systems into a variety of useful synthetic intermediates. In this work, we describe... Show more…
Grâce à leur réactivité particulière et à leurs propriétés caractéristiques, les radicaux alkoxyles constituent un outil puissant de la chimie organique moderne. Parmi leurs transformations typiques, les réactions de β-scission ont retenu notre attention. En effet, la conversion stéréoselective de systèmes bicycliques pontés, permet d’obtenir de nombreux intermédiaires synthétiques utiles.... Show more…
- Faculty
- Faculté des sciences
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
-
- RERO DOC 5328
- URN urn:nbn:ch:rero-002-101622
- RERO R003016745
- Persistent URL
- https://folia.unifr.ch/unifr/documents/299940