Doctoral thesis

Generation of alkoxyl radicals and their applications for ß-scission reactions in bridged bicyclic systems

  • Giraud, Anne
  • Renaud, Philippe (degree supervisor)
  • Cossy, Janine (degree supervisor)
    16.10.2000

138 p

Thèse de doctorat: Université de Fribourg, 2000

English French Due to their peculiar reactivity, alkoxyl radicals have unique characteristic properties, which make them powerful tools in modern organic chemistry. Among their typical transformations, β-scission reactions have retained our interest because of their potential in converting stereoselectively bridged bicyclic systems into a variety of useful synthetic intermediates. In this work, we describe... Show more… Grâce à leur réactivité particulière et à leurs propriétés caractéristiques, les radicaux alkoxyles constituent un outil puissant de la chimie organique moderne. Parmi leurs transformations typiques, les réactions de β-scission ont retenu notre attention. En effet, la conversion stéréoselective de systèmes bicycliques pontés, permet d’obtenir de nombreux intermédiaires synthétiques utiles.... Show more…
Faculty
Faculté des sciences
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/299940