Generation of alkoxyl radicals and their applications for ß-scission reactions in bridged bicyclic systems
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Giraud, Anne
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Renaud, Philippe (degree supervisor)
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Cossy, Janine (degree supervisor)
138 p
Thèse de doctorat: Université de Fribourg, 2000
English
French
Due to their peculiar reactivity, alkoxyl radicals have unique characteristic properties, which make them powerful tools in modern organic chemistry. Among their typical transformations, β-scission reactions have retained our interest because of their potential in converting stereoselectively bridged bicyclic systems into a variety of useful synthetic intermediates. In this work, we describe... Show more…
Grâce à leur réactivité particulière et à leurs propriétés caractéristiques, les radicaux alkoxyles constituent un outil puissant de la chimie organique moderne. Parmi leurs transformations typiques, les réactions de β-scission ont retenu notre attention. En effet, la conversion stéréoselective de systèmes bicycliques pontés, permet d’obtenir de nombreux intermédiaires synthétiques utiles.... Show more…
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Faculty
- Faculté des sciences
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Department
- Département de Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/299940