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advancedscience-2023-ochoamartinez-nanocrystallineflashannealednickeloxideforlargeareaperovskitesolar
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Nanocrystalline Flash Annealed Nickel Oxide for Large Area Perovskite Solar Cells

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  • Ochoa Martinez, Efrain ORCID Adolphe Merkle Institute, Chemin des Verdiers 4, University of Fribourg, 1700 Fribourg, Switzerland
  • Bijani‐Chiquero, Shanti ORCID Unidad de Nanotecnología Centro de Supercomputación y Bioinnovación SCBI Universidad de Málaga, Calle Severo Ochoa 34 Campanillas (Málaga) 29590 Spain
  • Martínez de Yuso, María del Valle ORCID Laboratorio de Espectroscopía de Fotoelectrones de Rayos‐X Servicios Centrales de Apoyo a la Investigación de la Universidad de Málaga, Málaga 29071 Spain
  • Sarkar, Subhrangsu ORCID Department of Physics and Fribourg Center for Nanomaterials, University of Fribourg, Chemin du Musée 3 Fribourg 1700 Switzerland
  • Diaz‐Perez, Horus ORCID Adolphe Merkle Institute, Chemin des Verdiers 4, University of Fribourg, 1700 Fribourg, Switzerland; Departamento de Ingeniería Eléctrica Universidad Nacional Autónoma de Honduras, Ciudad Universitaria Tegucigalpa 11101 Honduras
  • Mejia‐Castellanos, Roberto ORCID Departamento de Materia Condensada Escuela de Física, Universidad Nacional Autónoma de Honduras, Ciudad Universitaria Tegucigalpa 11101 Honduras
  • Eickemeyer, Felix ORCID Laboratory of Photonics and Interfaces, Institut des Sciences et Ingénierie Chimiques École Polytechnique Fédérale de Lausanne, Lausanne 1015 Switzerland
  • Grätzel, Michael ORCID Laboratory of Photonics and Interfaces, Institut des Sciences et Ingénierie Chimiques École Polytechnique Fédérale de Lausanne, Lausanne 1015 Switzerland
  • Steiner, Ullrich ORCID Adolphe Merkle Institute, Chemin des Verdiers 4, University of Fribourg, 1700 Fribourg, Switzerland
  • Milić, Jovana V. ORCID Adolphe Merkle Institute, Chemin des Verdiers 4, University of Fribourg, 1700 Fribourg, Switzerland
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  • 31.05.2023
Published in:
  • Advanced Science. - Wiley. - 2023, p. 2302549
General Physics and Astronomy
General Engineering
General Materials Science
General Chemical Engineering
flash infrared annealing
metal halide perovskites
nickel oxide
perovskite solar cells
English Abstract The industrialization of perovskite solar cells requires adequate materials and processes to make them economically viable and environmentally sustainable. Despite promising results in terms of power conversion efficiency and operational stability, several hole-transport layers currently in use still need to prove their industrial feasibility. This work demonstrates the use of nanocrystalline nickel oxide produced through flash infrared annealing (FIRA), considerably reducing the materials cost, production time, energy, and the amount of solvents required for the hole transport layer. X-ray photoelectron spectroscopy reveals a better conversion to nickel oxide and a higher oxygen-to-nickel ratio for the FIRA films as compared to control annealing methods, resulting in higher device efficiency and operational stability. Planar inverted solar cells produced with triple cation perovskite absorber result in 16.7\% power conversion efficiency for 1 cm2 devices, and 15.9\% averaged over an area of 17 cm2.
Faculty
Faculté des sciences et de médecine
Department
AMI - Physique de la matière molle
Language
  • English
Classification
Chemistry
License
CC BY
Open access status
gold
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/325299
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advs5751-sup-0001-suppmat
advs5751-sup-0002-suppcsv
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