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Nitrogen-doped carbons with hierarchical porosity via chemical blowing towards long-lived metal-free catalysts for acetylene hydrochlorination

  • Kaiser, Selina K. Institute for Chemical and Bioengineering Department of Chemistry and Applied BiosciencesETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland
  • Song, Kyung Seob Department of ChemistryUniversity of Fribourg Chemin de Musée 9 Fribourg 1700 Switzerland
  • Mitchell, Sharon Institute for Chemical and Bioengineering Department of Chemistry and Applied BiosciencesETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland
  • Coskun, Ali Department of ChemistryUniversity of Fribourg Chemin de Musée 9 Fribourg 1700 Switzerland
  • Pérez‐Ramírez, Javier Institute for Chemical and Bioengineering Department of Chemistry and Applied BiosciencesETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland
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    17.12.2019
Published in:
  • ChemCatChem. - 2020, vol. 12, no. 7, p. 1922-1925
English Porous nitrogen‐doped carbons (NCs) are sustainable alternatives to the toxic mercury‐based acetylene hydrochlorination catalysts applied in the manufacture of polyvinyl chloride. However, the application of NCs as metal‐free catalysts is hampered by their insufficient durability under industrially relevant process conditions. In particular, pore blockage leads to accelerated deactivation... Show more…
Faculty
Faculté des sciences et de médecine
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/308476
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