Betti bases from 4-(3-pyridazo)-1-naphthol: synthesis, coordination behaviour and unusual substitution reactions
- Kurteva, Vanya B. Institute of Organic Chemistry with Centre of Phytochemistry Bulgarian Academy of Sciences, Sofia, Bulgaria
- Lubenov, Lubomir A. Institute of Organic Chemistry with Centre of Phytochemistry Bulgarian Academy of Sciences, Sofia, Bulgaria
- Shivachev, Boris L. Institute of Mineralogy and Crystallography “Acad. Ivan Kostov” Bulgarian Academy of Sciences, Sofia, Bulgaria
- Nikolova, Rositsa P. Institute of Mineralogy and Crystallography “Acad. Ivan Kostov” Bulgarian Academy of Sciences, Sofia, Bulgaria
- Fromm, Katharina M. Department of Chemistry, University of Fribourg, Switzerland
-
2018
Published in:
- ChemistrySelect. - 2018, vol. 3, no. 43, p. 12017–12021
English
A series of Betti bases from 4‐(3‐pyridyl)azo‐1‐naphthol dye, possessing flexible methylene or more constrained aryl‐methyne spaced NH‐containing side‐chains, were obtained and characterized. It was shown by NMR spectroscopy that the ligands exist in keto form. The products’ structure was confirmed by single crystal XRD of a selected sample. A study on the coordination ability of the ligands with silver(I) was performed, leading to an unexpected substitution reaction.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
-
- RERO DOC 323823
- DOI 10.1002/slct.201802745
- Persistent URL
- https://folia.unifr.ch/unifr/documents/307409
Other files
Statistics
Document views: 24
File downloads:
- fro_bbf.pdf: 38
- fro_bbf_sm.pdf: 26