+ 1 other files
Synthesis of high molecular weight poly(p-benzamide)s
- Macromolecules. - 2017, vol. 50, no. 11, p. 4188–4197
The polymerization of aromatic para-amino acid ester derivatives was studied using model compounds. Mechanistic and kinetic experiments led to the discovery of some side reactions. Finally, high molecular weight poly(p-benzamide)s were synthesized and characterized. The use of highly reactive pentafluorophenol ester lead to polymers up to molecular weights of around 50 000 Da. Poly(benzamides) carrying both N-alkyl or N-benzyl groups on the amine could be polymerized to high molecular weight.
- Faculté des sciences et de médecine
- Département de Chimie
- kil_shm.pdf: 3
- kil_shm_sm.pdf: 1