Synthesis of high molecular weight poly(p-benzamide)s
- Badoux, Michael University of Fribourg, Chemistry Department, Fribourg, Switzerland
- Kilbinger, Andreas F. M. University of Fribourg, Chemistry Department, Fribourg, Switzerland
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13.06.2017
Published in:
- Macromolecules. - 2017, vol. 50, no. 11, p. 4188–4197
English
The polymerization of aromatic para-amino acid ester derivatives was studied using model compounds. Mechanistic and kinetic experiments led to the discovery of some side reactions. Finally, high molecular weight poly(p-benzamide)s were synthesized and characterized. The use of highly reactive pentafluorophenol ester lead to polymers up to molecular weights of around 50 000 Da. Poly(benzamides) carrying both N-alkyl or N-benzyl groups on the amine could be polymerized to high molecular weight.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 305127
- DOI 10.1021/acs.macromol.7b00515
- Persistent URL
- https://folia.unifr.ch/unifr/documents/306071
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