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Versatile reactivity and theoretical evaluation of mono- and dinuclear oxidovanadium(V) compounds of aroylazines: electrogeneration of mixed-valence divanadium(IV,V) complexes
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Dash, Subhashree P.
Department of Chemistry, National Institute of Technology, Odisha, India - Department of Chemistry, Indira Gandhi Institute of Technology, Sarang, Parjang, Dhenkanal, India
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Roy, Satabdi
Department of Chemistry, National Institute of Technology, Odisha, India
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Mohanty, Monalisa
Department of Chemistry, National Institute of Technology, Odisha, India
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Carvalho, M. Fernanda N. N.
Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Portugal
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Kuznetsov, Maxim L.
Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Portugal
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Pessoa, João Costa
Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Portugal
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Kumar, Amit
Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Portugal - Centre for Nano and Material Sciences, Jain University, Jain Global Campus, Bangalore, India
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Patil, Yogesh P.
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, India
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Crochet, Aurélien
Department of Chemistry, Fribourg Center for Nanomaterials, University of Fribourg, Switzerland
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Dinda, Rupam
Department of Chemistry, National Institute of Technology, Odisha, India
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Published in:
- Inorganic Chemistry. - 2016, vol. 55, no. 17, p. 8407–8421
English
The solution behavior of structurally characterized [VVO(OEt)(L)] complexes, which transform into the corresponding divanadium(V,V) compounds [{VVO(L)}₂-μ-O], is reported. Upon controlled potential electrolysis, the corresponding [(L)V₂O₃(L)]⁻ mixed-valence species are obtained upon partial reduction of the [(VVOL)₂-μ-O] formed in solution. All compounds are characterized in the solid state and solution by spectroscopic techniques and DFT calculations. The formation of V₂O₃³⁺ species is confirmed by the observation of a 15- line pattern in the EPR spectra at room temperature.
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Faculty
- Faculté des sciences et de médecine
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Department
- Département de Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/305002
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