Probing Mechanisms of Photochemical Reactions: How to Teach a Young Dog Old Tricks
Bochet, Christian G.Department of Chemistry, University of Fribourg, Switzerland
30.03.2016
Published in:
CHIMIA International Journal for Chemistry. - 2016, vol. 70, no. 3, p. 182-185
English
The mechanism of photochemical reactions can be difficult to study because of the very short-lived intermediates involved. State-of-the art ultrafast spectroscopic tools can be used to probe these processes, but we will show in this account that old- fashioned techniques, such as the determination of quantum yields, the measurement of isotope effects or the use of triplet quenchers and sensitizers still can give a significant insight into the mechanism of photochemical reactions.