Journal article

Healable Supramolecular Polymer Solids

Show more…
Published in:
  • Progress in Polymer Science. - 2015, vol. 49-50, p. 60-78
English The reversible nature of non-covalent interactions between constituting building blocks permits one to temporarily disassemble supramolecular polymers through the application of an appropriate external stimulus “on command”. This framework has recently emerged as a general design strategy for the development of healable polymer systems. The approach exploits that the temporary disassembly decreases the molecular weight and in the case of cross-linked polymers the cross-link density, and thereby causes an increase of the chain mobility and a reduction of the viscosity of the material. The transformation thus enables the disassembled material to flow and fill defects, before the original supramolecular polymer is re-assembled. Focusing on recent progress in the area of healable supramolecular polymer solids based on hydrogen-bonding, metal-ligand and π–π interactions, as well as supramolecular nanocomposites, this review article summarizes the development and current state of the field.
Faculté des sciences et de médecine
AMI - Chimie des polymères et matériaux
  • English
License undefined
Persistent URL

Document views: 41 File downloads:
  • Montero_Prog_Polym_Sci_HealableSMPs.pdf: 243