Spectroscopy of gold atoms isolated in liquid and solid ⁴He matrices
- Moroshkin, Peter Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg, Switzerland - Low Temperature Physics Laboratory, RIKEN, 2-1 Hirosawa, Wako, Saitama, Japan
- Lebedev, Victor Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg, Switzerland
- Weis, Antoine Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg, Switzerland
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10.09.2013
Published in:
- The Journal of Chemical Physics. - 2013, vol. 139, no. 10, p. 104307
English
We present a systematic experimental study of absorption and fluorescence spectra of Au atoms in bulk liquid and solid helium matrices. The results are compared to the spectra of Cu atoms studied earlier. We investigate the dependence of the observed spectral lineshapes on the helium pressure. The observed splitting of the 5d 106p − 5d 96s 2 transitions of Au in hcp solid He gives evidence for an anisotropic trapping site structure formed either by a non-spherical atomic bubble or a four-vacancy center.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Physique
- Language
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- English
- Classification
- Physics
- License
- License undefined
- Identifiers
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- RERO DOC 208651
- DOI 10.1063/1.4820398
- Persistent URL
- https://folia.unifr.ch/unifr/documents/303308
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