Layer-resolved study of Mg atom incorporation at the MgO/Ag(001) buried interface
Jaouen, ThomasDépartement de Physique and Fribourg Center for Nanomaterials, Université de Fribourg, Switzerland - Département Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
Tricot, S.Département Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
Delhaye, G.Département Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
Lépine, B.Département Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
Sébilleau, D.Département Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
Jézéquel, G.Département Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
Schieffer, PhilippeDépartement Matériaux Nanosciences, Institut de Physique, Université de Rennes, France
English
By combining x-ray excited Auger electron diffraction experiments and multiple scattering calculations we reveal a layer-resolved shift for the Mg KL₂₃L₂₃ Auger transition in MgO ultrathin films (4–6 Å) on Ag(001). This resolution is exploited to demonstrate the possibility of controlling Mg atom incorporation at the MgO/Ag(001) interface by exposing the MgO films to a Mg flux. A substantial reduction of the MgO/Ag(001) work function is observed during the exposition phase and reflects both band-offset variations at the interface and band bending effects in the oxide film.