Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands

Ristović, Maja Šumar; Pavlović, Maja Gruden; Zlatar, Matija; Blagojević, Vladimir; Anđelković, Katarina; Poleti, Dejan; Minić, Dragica M.

doi:10.1007/s00706-012-0793-6

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Journal article

Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands

Ristović, Maja Šumar Faculty of Chemistry, University of Belgrade, Serbia
Pavlović, Maja Gruden Faculty of Chemistry, University of Belgrade, Serbia
Zlatar, Matija Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Serbia - Department of Chemistry, University of Fribourg, Switzerland
Blagojević, Vladimir Faculty of Physical Chemistry, University of Belgrade, Serbia
Anđelković, Katarina Faculty of Chemistry, University of Belgrade, Serbia
Poleti, Dejan Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Serbia
Minić, Dragica M. Faculty of Physical Chemistry, University of Belgrade, Serbia

12.06.2012

Published in:

Monatshefte für Chemie - Chemical Monthly An International Journal of Chemistry. - 2012, vol. 143, no. 8, p. 1133-1139

English A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger–Akahira–Sunose’s method, and further analysis of these results was performed by Vyazovkin’s algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.

Faculty

Faculté des sciences et de médecine

Department

Département de Chimie

Language