Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands
- Ristović, Maja Šumar Faculty of Chemistry, University of Belgrade, Serbia
- Pavlović, Maja Gruden Faculty of Chemistry, University of Belgrade, Serbia
- Zlatar, Matija Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Serbia - Department of Chemistry, University of Fribourg, Switzerland
- Blagojević, Vladimir Faculty of Physical Chemistry, University of Belgrade, Serbia
- Anđelković, Katarina Faculty of Chemistry, University of Belgrade, Serbia
- Poleti, Dejan Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Serbia
- Minić, Dragica M. Faculty of Physical Chemistry, University of Belgrade, Serbia
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12.06.2012
Published in:
- Monatshefte für Chemie - Chemical Monthly An International Journal of Chemistry. - 2012, vol. 143, no. 8, p. 1133-1139
English
A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger–Akahira–Sunose’s method, and further analysis of these results was performed by Vyazovkin’s algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 29569
- DOI 10.1007/s00706-012-0793-6
- Persistent URL
- https://folia.unifr.ch/unifr/documents/302614
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