Efficient amine end-functionalization of living ring-Opening metathesis polymers
- Nagarkar, Amit A. Department of Chemistry, University of Fribourg, Switzerland
- Crochet, Aurélien Department of Chemistry, University of Fribourg, Switzerland
- Fromm, Katharina M. Department of Chemistry, University of Fribourg, Switzerland
- Kilbinger, Andreas F. M. Department of Chemistry, University of Fribourg, Switzerland
-
2012
Published in:
- Macromolecules. - 2012, vol. 45, no. 11, p. 4447–4453
English
An efficient strategy for the synthesis of monoamine end-functionalized living polymers using ring-opening metathesis polymerization with ruthenium initiators is reported. A new end-capping agent for this purpose was synthesized, and its efficiency for end-functionalization was evaluated using two common ruthenium-based initiators. Finally, terminal cross-metathesis was also explored as another alternative toward the synthesis of amine end-functionalized polymers, and the comparison between the two techniques is presented.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 29567
- DOI 10.1021/ma300602p
- Persistent URL
- https://folia.unifr.ch/unifr/documents/302592
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