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The spectroscopy and thermochemistry of phenylallyl radical chromophores

  • Troy, Tyler P. School of Chemistry,The University of Sydney, Australia
  • Chalyavi, Nahid School of Chemistry,The University of Sydney, Australia
  • Menon, Ambili S. School of Chemistry,The University of Sydney, Australia - ARC Centre of Excellence for Free Radical Chemistry and Biotechnology, Australia - Department of Chemistry, University of Fribourg, Switzerland
  • O'Connor, Gerard D. School of Chemistry,The University of Sydney, Australia
  • Fückel, Burkhard School of Chemistry,The University of Sydney, Australia
  • Nauta, Klaas School of Chemistry,The University of Sydney, Australia
  • Radom, Leo School of Chemistry,The University of Sydney, Australia - ARC Centre of Excellence for Free Radical Chemistry and Biotechnology, Australia
  • Schmidt, Timothy W. School of Chemistry,The University of Sydney, Australia
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    27.06.2007
Published in:
  • Chemical Science. - 2011, vol. 2, no. 9, p. 1755-1765
English The resonant two-color two-photon ionization and laser induced fluorescence excitation spectra of the 1-phenylallyl (cinnamyl) and inden-2-ylmethyl radicals are reported. The 1-phenylallyl radical is found to fluoresce with low yield, permitting only a coarse dispersed fluorescence spectrum, while the inden-2-ylmethyl radical yields sufficient fluorescence to obtain ground-state vibrational frequencies and two-dimensional fluorescence spectra. Computed ionization energies and thermochemical properties including radical stabilization energies are reported for a range of resonance-stabilized radicals, including the phenylpropargyl, vinylpropargyl and phenylallyl radicals.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/302052
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