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Synthesis and catalytic activity of histidine-based NHC ruthenium complexes

  • Monney, Angèle School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland - Department of Chemistry, University of Fribourg, Switzerland
  • Venkatachalam, Galmari Department of Chemistry, University of Fribourg, Switzerland
  • Albrecht, Martin School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland - Department of Chemistry, University of Fribourg, Switzerland
    16.02.2011
Published in:
  • Dalton Transactions. - 2011, vol. 40, no. 12, p. 2716-2719
English Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired complexes show appreciable activity in the catalytic transfer hydrogenation of ketones.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Biology
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/301907
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