Synthesis and catalytic activity of histidine-based NHC ruthenium complexes
- Monney, Angèle School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland - Department of Chemistry, University of Fribourg, Switzerland
- Venkatachalam, Galmari Department of Chemistry, University of Fribourg, Switzerland
- Albrecht, Martin School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland - Department of Chemistry, University of Fribourg, Switzerland
-
16.02.2011
Published in:
- Dalton Transactions. - 2011, vol. 40, no. 12, p. 2716-2719
English
Main-chain C,N-protected histidine has been successfully alkylated at both side-chain nitrogens. The corresponding histidinium salt was metallated with ruthenium(II) by a transmetalation procedure, thus providing histidine-derived NHC ruthenium complexes. These bio-inspired complexes show appreciable activity in the catalytic transfer hydrogenation of ketones.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Biological sciences
- License
- License undefined
- Identifiers
-
- RERO DOC 22501
- DOI 10.1039/c0dt01768j
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301907
Other files
Statistics
Document views: 53
File downloads:
- mon_sca.pdf: 111
- mon_sca_sm.pdf: 110