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Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

  • Kitchen, Jonathan A. Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, Dunedin, New Zealand
  • White, Nicholas G. Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, Dunedin, New Zealand
  • Gandolfi, Claudio Department of Chemistry, University of Fribourg, Switzerland
  • Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland - School of Chemistry and Chemical Biology, University College Dublin, Belfield, Ireland
  • Jameson, Guy N. L. Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, Dunedin, New Zealand
  • Tallon, Jeffery L. MacDiarmid Institute for Advanced Materials and Nanotechnology and Industrial Research Limited, Lower Hutt, New Zealand
  • Brooker, Sally Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, Dunedin, New Zealand
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    07.07.2010
Published in:
  • Chemical Communications. - 2010, vol. 46, no. 35, p. 6464-6466
English [FeII(C₁₆dpt)₂(NCS)₂]·⅔H₂O displays temperature-mediated spin crossover (SCO) with T½ = 290 K and the long alkyl chain substituent on the dipyridyltriazole ligand facilitates the formation of a stable Langmuir–Blodgett film at an air–water interface.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/301783
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