Radicals and radical ions derived from indole, indole-3-carbinol and diindolylmethane
- Błoch-Mechkour, Anna Department of Chemistry, University of Fribourg, Switzerland
- Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
- Sikora, Adam Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
- Michalski, Radosław Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
- Marcinek, Andrzej Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
- Gębicki, Jerzy Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
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04.06.2010
Published in:
- The Journal of Physical Chemistry A. - 2010, vol. 114, no. 25, p. 6787–6794
English
The primary products, i.e., the radical cations and radicals obtained on oxidation of the glucobrassicin metabolites (and dietary supplements), indole-3-carbinol (I3C) and diindolylmethane (DIM), and those from parent indole (I) are characterized in an ionic liquid and in Ar matrices. The radical cations of I and I3C are stable toward (photo)deprotonation under these conditions, but the resulting radicals can be generated by UV-photolysis of the neutral precursors. Two types of radicals, obtained by loss of hydrogen from N- and C-atoms, respectively, are found for I3C and DIM.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 20722
- DOI 10.1021/jp912121y
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301734
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