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Radicals and radical ions derived from indole, indole-3-carbinol and diindolylmethane

  • Błoch-Mechkour, Anna Department of Chemistry, University of Fribourg, Switzerland
  • Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
  • Sikora, Adam Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
  • Michalski, Radosław Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
  • Marcinek, Andrzej Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
  • Gębicki, Jerzy Institute of Applied Radiation Chemistry, Technical University, Lodz, Poland
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    04.06.2010
Published in:
  • The Journal of Physical Chemistry A. - 2010, vol. 114, no. 25, p. 6787–6794
English The primary products, i.e., the radical cations and radicals obtained on oxidation of the glucobrassicin metabolites (and dietary supplements), indole-3-carbinol (I3C) and diindolylmethane (DIM), and those from parent indole (I) are characterized in an ionic liquid and in Ar matrices. The radical cations of I and I3C are stable toward (photo)deprotonation under these conditions, but the resulting radicals can be generated by UV-photolysis of the neutral precursors. Two types of radicals, obtained by loss of hydrogen from N- and C-atoms, respectively, are found for I3C and DIM.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/301734
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