Multitopic ligand design: a concept for single-source precursors
- Gschwind, Fabienne University of Fribourg, Department of Chemistry, Switzerland
- Sereda, Olha CSEM Centre Suisse d'Electronique et de Microtechnique, Neuchâtel, Switzerland
- Fromm, Katharina M. University of Fribourg, Department of Chemistry, Switzerland
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14.10.2009
Published in:
- Inorganic Chemistry. - 2009, vol. 48, no. 22, p. 10535–10547
English
The multitopic ligand O,O′-bisnicotinic acid tetraethylene glycol, L, was designed for the coordination of two distinct types of metal ions. In this work, we describe how the O-donor part of L is used to coordinate to alkaline earth metal ions and that the N-donor atoms of L bind to group 11 elements. This makes L a suitable ligand for the combination of both metal ion types within the same compound. This concept will be exemplified by highlighting the pure Ca²⁺ complexes, a Cu⁺-coordination polymer network, as well as the mixed-metal compound, which can be used as a single-source precursor for mixed-metal oxide materials.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 13172
- DOI 10.1021/ic9009064
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301246
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