Abnormal carbenes as ligands in transition metal chemistry: curiosities with exciting perspectives

Albrecht, Martin

doi:10.2533/chimia.2009.105

Back

Journal article

Abnormal carbenes as ligands in transition metal chemistry: curiosities with exciting perspectives

Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland

2009

Published in:

Chimia. - 2009, vol. 63, no. 3, p. 105-110

English This review compiles the advances achieved in our laboratories using abnormal and less heteroatom-stabilized carbenes as ligands for transition metal chemistry. Fundamental studies allowed the evaluation of the impact of this new class of ligands both electronically and sterically. Based on these results, initial catalytic applications have been devised in the area of H-H and C-H bond activation, demonstrating the potential of abnormal carbenes as unique ligands for transition metals.

Faculty

Faculté des sciences et de médecine

Department

Département de Chimie

Language