Abnormal carbenes as ligands in transition metal chemistry: curiosities with exciting perspectives
- Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland
-
2009
Published in:
- Chimia. - 2009, vol. 63, no. 3, p. 105-110
abnormal coordination mode
catalytic applications
n-heterocyclic carbenes
late transition metals
metal nucleophilicity
English
This review compiles the advances achieved in our laboratories using abnormal and less heteroatom-stabilized carbenes as ligands for transition metal chemistry. Fundamental studies allowed the evaluation of the impact of this new class of ligands both electronically and sterically. Based on these results, initial catalytic applications have been devised in the area of H-H and C-H bond activation, demonstrating the potential of abnormal carbenes as unique ligands for transition metals.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
-
- RERO DOC 12221
- DOI 10.2533/chimia.2009.105
- Persistent URL
- https://folia.unifr.ch/unifr/documents/301152
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