Photochemistry of allenyl salicylaldehydes
- Birbaum, Frédéric Department of Chemistry, University of Fribourg,Switzerland
- Neels, Antonia Institut de Microtechnique, University of Neuchâtel, Switzerland
- Bochet, Christian G. Department of Chemistry, University of Fribourg,Switzerland
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03.07.2008
Published in:
- Organic Letters. - 2008, vol. 10, no. 15, p. 3175–3178
English
The intramolecular photocycloaddition of aryl aldehydes containing allene side chains is a versatile reaction as it provides a rapid and efficient access to original complex structures such as 1,3,4-tetrahydro-1,4-epoxy-5-alkylidene-2-benzoxepines 2 and substituted 2-oxa-tricyclo[5.2.2.0]1,5undeca-4,8,10-triene-9-carbaldehydes 3. Novel polycyclic structures are characterized, and optimized strategies for the synthesis of the substrates 1 are described.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 9728
- DOI 10.1021/ol800806a
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300880
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