C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands
- Albrecht, Martin Department of Chemistry, University of Fribourg, Switzerland
-
28.07.2008
Published in:
- Chemical Communications. - 2008, p. 3601-3610
English
This feature article summarizes the progress achieved thus far in using C4-bound imidazolylidenes as a new class of ligands for transition metals. Since the discovery of this unusual carbene bonding mode in 2001, various rational routes towards complexes containing C4-bound carbenes have evolved. These advances allowed for studying the impact of this new type of ligand on the transition metal center, both from a fundamental point of view as well as from a more applied perspective, in particular for catalytic applications. The promising results accomplished in this relatively short period of time demonstrate the potential of C4-bound imidazolylidenes as unique carbene ligands for inducing catalytic activity and for mediating unprecedented transformations.
- Faculty
- Faculté des sciences et de médecine
- Department
- Département de Chimie
- Language
-
- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 9725
- DOI 10.1039/b806924g
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300836
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