Cobalt substituted ZnO thin films: a potential candidate for spintronics
Bhatti, Kanwal PreetThin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi, India
Malik, Vivek KumarDepartment of Physics, University of Fribourg, Switzerland
Chaudhary, SujeetThin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi, India
05.12.2007
Published in:
Journal of Materials Science: Materials in Electronics. - 2008, vol. 19, no. 8-9, p. 849-854
English
Cobalt doped zinc oxide thin films have been deposited using spray pyrolysis method. These single phasic films exhibited [100] preferential texture and small decrease in the lattice parameter on cobalt substitution. The films having different Co concentration have almost similar surface morphology and microstructure. These Zn1−xCoxO (x ≤ 0.10) thin films distinctly showed ferromagnetic character at room temperature. The optical transmission measurements of these films clearly proved that in these films Co substitutes for Zn²⁺ and exists in +2 state. Based on the optical, structural and magnetic measurements, the possibility of occurrence of ferromagnetic ordering due to cobalt clustering is ruled out in these spray-pyrolyzed films. A correlation of the observed ferromagnetic behavior in these Zn1−xCoxO films with structural change resulting from the addition of Co is presented in this paper.