Cleavage of the ether bond by electron impact: differences between linear ethers and tetrahydrofuran
- Ibănescu, Bogdan C. Department of Chemistry, University of Fribourg, Switzerland
- May, Olivier Department of Chemistry, University of Fribourg, Switzerland
- Allan, Michael Department of Chemistry, University of Fribourg, Switzerland
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24.01.2008
Published in:
- Physical Chemistry Chemical Physics. - 2008, vol. 10, p. 1507-1511
English
Dissociative electron attachment (DEA) to diethyl ether yielded primarily the C₂H₅O⁻ ion, with a strong Feshbach resonance band at 9.1 eV and a weaker shape resonance band at 3.89 eV. Very similar spectra were obtained for dibutyl ether, with C₄H₉O⁻ bands at 8.0 and 3.6 eV. Some of these primary ions subsequently lost H₂ and yielded weaker signals of the C₂H₃O⁻ and C₄H₇O⁻ ions. In contrast,... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 9242
- DOI 10.1039/b718130b
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300631