Analogy of the Coordination Chemistry of Alkaline Earth Metal and Lanthanide Ln²⁺ Ions: The Isostructural Zoo of Mixed Metal Cages [IM(OtBu)₄{Li(thf)}₄(OH)] (M=Ca, Sr, Ba, Eu), [MM′₆(OPh)₈(thf)₆] (M=Ca, Sr, Ba, Sm, Eu, M′=Li, Na), and their Derivatives with 1,2-Dimethoxyethane
- Maudez, William Department of Chemistry, University of Basel, Switzerland
- Meuwly, Markus Department of Chemistry, University of Basel, Switzerland
- Fromm, Katharina M. Department of Chemistry, University of Fribourg, Switzerland
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17.07.2007
Published in:
- Chemistry - A European Journal. - 2007, vol. 13, no. 29, p. 8302 - 8316
aggregation
alkaline earth metals
cage compounds
cluster compounds
lanthanides
solid-state structures
English
As previously shown, alkali and alkaline earth metal iodides in nonaqueous, aprotic solvents behave like transition metal halides, forming <i>cis</i>- and <i>trans</i>-dihalides with various neutral O-donor ligands. These compounds can be used as precursors for the synthesis of new mixed alkali/alkaline earth metal aggregates. We show here that Ln²⁺ ions form isostructural cluster compounds.... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 8850
- DOI 10.1002/chem.200700597
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300594