Journal article

Matrix isolation and computational study of the photochemistry of 1,3,2,4-Benzodithiadiazine

  • Gritsan, Nina P. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia - Novosibirsk State University, Russia
  • Pritchina, Elena A. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia - Novosibirsk State University, Russia
  • Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
  • Makarov, Alexander Yu. Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
  • Zibarev, Andrey V. Novosibirsk State University, Russia - Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
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    17.01.2007
Published in:
  • The Journal of Physical Chemistry A. - 2007, vol. 111, no. 5, p. 817 -824
English Photolysis of 1,3,2,4-benzodithiadiazine (1) at ambient temperature yields stable 1,2,3-benzodithiazolyl radicals. In order to reveal the mechanism of this unusual transformation, the photochemistry of 1 was studied in argon matrices using IR and UV-vis spectroscopy. A series of intermediates, including four- and five-membered heterocyclic and o-quinoid acyclic species, were characterized... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/300557