Matrix isolation and computational study of the photochemistry of 1,3,2,4-Benzodithiadiazine
- Gritsan, Nina P. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia - Novosibirsk State University, Russia
- Pritchina, Elena A. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia - Novosibirsk State University, Russia
- Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
- Makarov, Alexander Yu. Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
- Zibarev, Andrey V. Novosibirsk State University, Russia - Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
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17.01.2007
Published in:
- The Journal of Physical Chemistry A. - 2007, vol. 111, no. 5, p. 817 -824
English
Photolysis of 1,3,2,4-benzodithiadiazine (1) at ambient temperature yields stable 1,2,3-benzodithiazolyl radicals. In order to reveal the mechanism of this unusual transformation, the photochemistry of 1 was studied in argon matrices using IR and UV-vis spectroscopy. A series of intermediates, including four- and five-membered heterocyclic and o-quinoid acyclic species, were characterized... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 8846
- DOI 10.1021/jp063977k
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300557