Mechanistic aspects of the oxidative and reductive fragmentation of n-nitrosoamines: a new method for generating nitrenium cations, amide anions, and aminyl radicals
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Piech, Krzysztof
Department of Chemistry, University of Fribourg, Switzerland
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Bally, Thomas
Department of Chemistry, University of Fribourg, Switzerland
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Sikora, Adam
Institute of Applied Radiation Chemistry, Technical University of Lodz, Poland
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Marcinek, Andrzej
Institute of Applied Radiation Chemistry, Technical University of Lodz, Poland
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Published in:
- Journal of the American Chemical Society. - 2007, vol. 129, no. 11, p. 3211 -3217
English
A new method for investigating the mechanisms of nitric oxide release from NO donors under oxidative and reductive conditions is presented. Based on the fragmentation of <i>N</i>-nitrosoamines, it allows generation and spectroscopic characterization of nitrenium cations, amide anions, and aminyl radicals. X-irradiation of <i>N</i>-nitroso-<i>N</i>,<i>N</i>-diphenylamine <b>1</b> in Ar matrices... Show more…
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Faculty
- Faculté des sciences
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Department
- Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/300543