Mechanistic aspects of the oxidative and reductive fragmentation of n-nitrosoamines: a new method for generating nitrenium cations, amide anions, and aminyl radicals
- Piech, Krzysztof Department of Chemistry, University of Fribourg, Switzerland
- Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
- Sikora, Adam Institute of Applied Radiation Chemistry, Technical University of Lodz, Poland
- Marcinek, Andrzej Institute of Applied Radiation Chemistry, Technical University of Lodz, Poland
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01.03.2007
Published in:
- Journal of the American Chemical Society. - 2007, vol. 129, no. 11, p. 3211 -3217
English
A new method for investigating the mechanisms of nitric oxide release from NO donors under oxidative and reductive conditions is presented. Based on the fragmentation of <i>N</i>-nitrosoamines, it allows generation and spectroscopic characterization of nitrenium cations, amide anions, and aminyl radicals. X-irradiation of <i>N</i>-nitroso-<i>N</i>,<i>N</i>-diphenylamine <b>1</b> in Ar matrices... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 8845
- DOI 10.1021/ja066855e
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300543