Journal article

Mechanistic aspects of the oxidative and reductive fragmentation of n-nitrosoamines: a new method for generating nitrenium cations, amide anions, and aminyl radicals

  • Piech, Krzysztof Department of Chemistry, University of Fribourg, Switzerland
  • Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
  • Sikora, Adam Institute of Applied Radiation Chemistry, Technical University of Lodz, Poland
  • Marcinek, Andrzej Institute of Applied Radiation Chemistry, Technical University of Lodz, Poland
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    01.03.2007
Published in:
  • Journal of the American Chemical Society. - 2007, vol. 129, no. 11, p. 3211 -3217
English A new method for investigating the mechanisms of nitric oxide release from NO donors under oxidative and reductive conditions is presented. Based on the fragmentation of <i>N</i>-nitrosoamines, it allows generation and spectroscopic characterization of nitrenium cations, amide anions, and aminyl radicals. X-irradiation of <i>N</i>-nitroso-<i>N</i>,<i>N</i>-diphenylamine <b>1</b> in Ar matrices... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/300543