1,4-Dimethylenespiropentane: a unique model system for studying fermi resonance in raman optical activity
- Hug, Werner Department of Chemistry, University of Fribourg, Switzerland
- Haesler, Jacques Department of Chemistry, University of Fribourg, Switzerland
- Kozhushkov, Sergei I. Institut für Organische und Biomolekulare Chemie der Georg-August-Universität Göttingen, Germany
- Meijere, Armin de Institut für Organische und Biomolekulare Chemie der Georg-August-Universität Göttingen, Germany
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11.05.2007
Published in:
- ChemPhysChem. - 2007, vol. 8, no. 8, p. 1161 - 1169
English
The C₂-symmetric title compound, a small, rigid hydrocarbon molecule with two distinct, strongly interacting vibrational chromophores, represents a unique model system for testing computational approaches to Raman optical activity (ROA) beyond the isolated molecule and the harmonic approximation. We show that the experimental Raman and ROA spectra are marked by the presence of strong Fermi... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 8124
- DOI 10.1002/cphc.200600678
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300464