Journal article

From simple rings to one-dimensional channels with calix[8]arenes, water clusters, and alkali metal ions

  • Bergougnant, Rémi D. Department of Chemistry, University of Fribourg, Switzerland
  • Robin, Adeline Y. Department of Chemistry, University of Fribourg, Switzerland
  • Fromm, Katharina M. Department of Chemistry, University of Fribourg, Switzerland
    20.07.2007
Published in:
  • Tetrahedron. - 2007, vol. 63, no. 44, p. 10751-10757
English The macrocycle 4-<i>tert</i>-butylcalix[8]arene (L) was reacted with alkali metal carbonates (Li₂CO₃, Na₂CO₃, K₂CO₃, Rb₂CO₃, and Cs₂CO₃) at the interface of a biphasic THF/water system. Needle-like crystals with a general formula [A<i><sub>x</sub></i>(4-<i>tert</i>-butylcalix[8]arene-<i>x</i>H)(THF)<i><sub>y</sub></i>(H₂O)<i><sub>z</sub></i>] (with A=Li, Na, K, Rb, Cs, <i>x</i>=1, 2,... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/300451