Mild and rational synthesis of palladium complexes comprising C(4)-bound N-heterocyclic carbenes
Kluser, EvelyneChemistry Department, University of Fribourg, Switzerland
Neels, AntoniaInstitute of Microtechnology, University of Neuchâtel, Switzerland
Albrecht, MartinChemistry Department, University of Fribourg, Switzerland
15.09.2006
Published in:
Chemical Communications. - 2006, p. 4495-4497
English
Oxidative addition of pyridyl-functionalised 4-iodoimidazolium salts to palladium(0) gives catalytically active complexes in which the N-heterocyclic carbene is bound to the palladium(II) centre in a non-classical bonding mode via C(4).