Matrix isolation and computational study of the photochemistry of p-azidoaniline
- Pritchina, Elena A. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences and Novosibirsk State University, Novosibirsk, Russia
- Gritsan, Nina P. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences and Novosibirsk State University, Novosibirsk, Russia
- Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
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2006
Published in:
- Physical Chemistry Chemical Physics. - 2006, vol. 8, p. 719-727
English
The photochemistry of <i>p</i>-azidoaniline was studied in argon matrices in the absence and presence of oxygen. With the help of quantum chemical calculations we were able to characterize the triplet <i>p</i>-aminophenylnitrene as well as the <i>cis- </i> and <i>trans</i>-<i>p</i>-aminophenylnitroso oxides. It was found that the latter two isomers can be interconverted by selective... Show more…
- Faculty
- Faculté des sciences et de médecine
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 5729
- DOI 10.1039/b511229j
- Persistent URL
- https://folia.unifr.ch/unifr/documents/300131