Journal article

Matrix isolation and computational study of the photochemistry of p-azidoaniline

  • Pritchina, Elena A. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences and Novosibirsk State University, Novosibirsk, Russia
  • Gritsan, Nina P. Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences and Novosibirsk State University, Novosibirsk, Russia
  • Bally, Thomas Department of Chemistry, University of Fribourg, Switzerland
    2006
Published in:
  • Physical Chemistry Chemical Physics. - 2006, vol. 8, p. 719-727
English The photochemistry of <i>p</i>-azidoaniline was studied in argon matrices in the absence and presence of oxygen. With the help of quantum chemical calculations we were able to characterize the triplet <i>p</i>-aminophenylnitrene as well as the <i>cis- </i> and <i>trans</i>-<i>p</i>-aminophenylnitroso oxides. It was found that the latter two isomers can be interconverted by selective... Show more…
Faculty
Faculté des sciences et de médecine
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/300131