Journal article

Stereoselectivity in the formation of tris-diimine complexes of Fe(II), Ru(II), and Os(II) with a C-symmetric chiral derivative of 2,2′-bipyridine

  • Drahoňovský, Dušan Department of Chemistry, University of Fribourg, Switzerland
  • Knof, Ulrich Department of Chemistry, University of Fribourg, Switzerland
  • Jungo, Laurence Department of Chemistry, University of Fribourg, Switzerland
  • Belser, Thomas Department of Chemistry, University of Fribourg, Switzerland
  • Neels, Antonia Institute of Chemistry, University of Neuchâtel, Switzerland
  • Labat, Gaël Charles Institute of Chemistry, University of Neuchâtel, Switzerland
  • Stoeckli-Evans, Helen Institute of Chemistry, University of Neuchâtel, Switzerland
  • Zelewsky, Alexander von Department of Chemistry, University of Fribourg, Switzerland
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    2006
Published in:
  • Dalton Transactions. - 2006, p. 1444 - 1454
English A <i>C</i>₂-symmetric enantiopure 4,5-bis(pinene)-2,2′-bipyridine ligand (–)-L was used to investigate the diastereoselectivity in the formation of [ML₃]²⁺ coordination species (M = Fe(II), Ru(II), Os(II), Zn(II), Cd(II), Cu(II), Ni(II)), and [ML₂Cl₂] (M = Ru(II), Os(II)). The X-ray structures of the [ML₃]²⁺ complexes were determined for Δ-[FeL₃](PF₆)₂, Δ-[RuL₃](PF₆)₂, Λ-[RuL₃](PF₆)₂,... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/300101