Synthesis and Stereochemical Properties of Chiral Square Complexes of Iron(II)
- Bark, Thomas Department of Chemistry of the University of Fribourg, Switzerland
- Zelewsky, Alexander von Department of Chemistry of the University of Fribourg, Switzerland
- Rappoport, Dmitrij Institute of Physical Chemistry, University of Karlsruhe, Germany
- Neuburger, Markus Laboratory for Chemical Crystallography, University of Basel, Switzerland
- Schaffner, Silvia Laboratory for Chemical Crystallography, University of Basel, Switzerland
- Lacour, Jérôme Department of Organic Chemistry, University of Geneva, Switzerland
- Jodry, Jonathan Department of Organic Chemistry, University of Geneva, Switzerland
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17.08.2004
Published in:
- Chemistry - A European Journal. - 2004, vol. 10(19), p. 4839-4845
chiral resolution
density functional calculations
diastereoselectivity
iron
molecular squares
self-assembly
English
German
The hexadentate, and ditopic ligand 2,5-bis([2,2']bipyridin-6-yl)pyrazine yields a chiral, tetrameric, square-shaped, self-assembled species upon complexation with Fe²⁺ ions. The racemate of this complex was resolved with antimonyl tatrate as the chiral auxiliary. The purity of the enantiomer was determined by NMR spectroscopy, by using a chiral, diamagnetic shift reagent, and by circular... Show more…
Der hexadentate und ditopische Ligand 2,5-Bis([2,2']bipyridin-6-yl)pyrazin bildet bei der Selbstorganisationsreaktion mit Fe²⁺-Ionen einen chiralen, quadratförmigen Tetramerkomplex. Das Racemat dieses Komplexes wurde mit Hilfe von Antimonyltartrat in die Enantiomere getrennt. Die Reinheit des Enantiomers wurde durch NMR-Spektroskopie unter Zuhilfenahme eines chiralen, diamagnetischen... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 4820
- DOI 10.1002/chem.200400399
- Persistent URL
- https://folia.unifr.ch/unifr/documents/299603