Journal article

Complexation behaviour of chiral tetradentate polypyridines derived from α-pinene

    28.08.2004
Published in:
  • Inorganica Chimica Acta. - 2005, vol. 358(1), p. 41-49
English A series of ligands, where two pinene-bipyridine moieties are either connected directly, or through a p-xylene bridge are investigated with respect to their complexation behaviour in solution. The bridged [5,6]-CHIRAGEN[p-xyl] ligands, which are substituted in 5' or 6' positions show self-assembly reactions, which lead to similar supramolecular species as the unsubstituted bis-pinene-bipyridines ligands studied before. The directly connected [5,6]-CHIRAGEN[0] derivatives, which are substituted at positions 5' or 6', form mononuclear complexes with helical chirality at the metal centre.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/299589
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