Radical Cations of Phenyl-Substituted Aziridines: What Are the Conditions for Ring Opening ?
- Gaebert, Carsten Fakultät für Chemie, Universität Bielefeld, Germany - Present address: Consortium für elektrochemische Industrie GmbH, München, Germany
- Mattay, Jochen Fakultät für Chemie, Universität Bielefeld, Germany
- Toubartz, Marion Max-Planck-Institut für Bioanorganische Chemie, Mülheim/Ruhr, Germany
- Steenken, Steen Max-Planck-Institut für Bioanorganische Chemie, Mülheim/Ruhr, Germany
- Müller, Beat Departement de Chimie, Université de Fribourg, Switzerland - Present address: Bundesamt für Umwelt, Wald und Landschaft, Bern, Switzerland
- Bally, Thomas Departement de Chimie, Université de Fribourg, Switzerland
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02.01.2005
Published in:
- Chemistry - A European Journal. - 2005, vol. 11(4), no. 1294-1304
English
Radical cations were generated from different phenyl-substituted aziridines by pulse radiolysis in aqueous solution containing TlOH<sup>.+</sup>, N₃<sup>.</sup> or SO₄<sup>.-</sup> as oxidants or in n-butyl chloride, by ⁶⁰Co γ radiolysis in Freon matrices at 77 K, and in some cases by flash photolysis in aqueous solution. Depending on the substitution pattern of the aziridines, two different... Show more…
- Faculty
- Faculté des sciences
- Department
- Chimie
- Language
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- English
- Classification
- Chemistry
- License
- License undefined
- Identifiers
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- RERO DOC 4816
- DOI 10.1002/chem.200400557
- Persistent URL
- https://folia.unifr.ch/unifr/documents/299563