Radical Cations of Phenyl-Substituted Aziridines: What Are the Conditions for Ring Opening ?
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Gaebert, Carsten
Fakultät für Chemie, Universität Bielefeld, Germany - Present address: Consortium für elektrochemische Industrie GmbH, München, Germany
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Mattay, Jochen
Fakultät für Chemie, Universität Bielefeld, Germany
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Toubartz, Marion
Max-Planck-Institut für Bioanorganische Chemie, Mülheim/Ruhr, Germany
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Steenken, Steen
Max-Planck-Institut für Bioanorganische Chemie, Mülheim/Ruhr, Germany
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Müller, Beat
Departement de Chimie, Université de Fribourg, Switzerland - Present address: Bundesamt für Umwelt, Wald und Landschaft, Bern, Switzerland
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Bally, Thomas
Departement de Chimie, Université de Fribourg, Switzerland
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Published in:
- Chemistry - A European Journal. - 2005, vol. 11(4), no. 1294-1304
English
Radical cations were generated from different phenyl-substituted aziridines by pulse radiolysis in aqueous solution containing TlOH<sup>.+</sup>, N₃<sup>.</sup> or SO₄<sup>.-</sup> as oxidants or in n-butyl chloride, by ⁶⁰Co γ radiolysis in Freon matrices at 77 K, and in some cases by flash photolysis in aqueous solution. Depending on the substitution pattern of the aziridines, two different... Show more…
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Faculty
- Faculté des sciences
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Department
- Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/unifr/documents/299563