Journal article

Radical Cations of Phenyl-Substituted Aziridines: What Are the Conditions for Ring Opening ?

  • Gaebert, Carsten Fakultät für Chemie, Universität Bielefeld, Germany - Present address: Consortium für elektrochemische Industrie GmbH, München, Germany
  • Mattay, Jochen Fakultät für Chemie, Universität Bielefeld, Germany
  • Toubartz, Marion Max-Planck-Institut für Bioanorganische Chemie, Mülheim/Ruhr, Germany
  • Steenken, Steen Max-Planck-Institut für Bioanorganische Chemie, Mülheim/Ruhr, Germany
  • Müller, Beat Departement de Chimie, Université de Fribourg, Switzerland - Present address: Bundesamt für Umwelt, Wald und Landschaft, Bern, Switzerland
  • Bally, Thomas Departement de Chimie, Université de Fribourg, Switzerland
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    02.01.2005
Published in:
  • Chemistry - A European Journal. - 2005, vol. 11(4), no. 1294-1304
English Radical cations were generated from different phenyl-substituted aziridines by pulse radiolysis in aqueous solution containing TlOH<sup>.+</sup>, N₃<sup>.</sup> or SO₄<sup>.-</sup> as oxidants or in n-butyl chloride, by ⁶⁰Co γ radiolysis in Freon matrices at 77 K, and in some cases by flash photolysis in aqueous solution. Depending on the substitution pattern of the aziridines, two different... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/unifr/documents/299563