Journal article
Radicals and radical ions derived from indole, indole-3-carbinol and diindolylmethane.
- Błoch-Mechkour A Department of Chemistry, University of Fribourg, CH-1700 Fribourg, Switzerland.
- Bally T
- Sikora A
- Michalski R
- Marcinek A
- Gebicki J
- 2010-06-08
Published in:
- The journal of physical chemistry. A. - 2010
English
The primary products, i.e., the radical cations and radicals obtained on oxidation of the glucobrassicin metabolites (and dietary supplements), indole-3-carbinol (I3C) and diindolylmethane (DIM), and those from parent indole (I) are characterized in an ionic liquid and in Ar matrices. The radical cations of I and I3C are stable toward (photo)deprotonation under these conditions, but the resulting radicals can be generated by UV-photolysis of the neutral precursors. Two types of radicals, obtained by loss of hydrogen from N- and C-atoms, respectively, are found for I3C and DIM.
- Language
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- English
- Open access status
- closed
- Identifiers
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- DOI 10.1021/jp912121y
- PMID 20524680
- Persistent URL
- https://folia.unifr.ch/global/documents/98345
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