Journal article
Metal-peptide frameworks (MPFs): "bioinspired" metal organic frameworks.
- Mantion A Department of Chemistry, Klingelbergstrasse 80, University of Basel, CH-4056 Basel, Switzerland. a.mantion@unibas.ch
- Massüger L
- Rabu P
- Palivan C
- McCusker LB
- Taubert A
- 2008-02-06
Published in:
- Journal of the American Chemical Society. - 2008
Biomimetic Materials
Calcium
Copper
Crystallography, X-Ray
Hydrogen Bonding
Ligands
Models, Molecular
Molecular Conformation
Organometallic Compounds
Peptides
Porosity
Surface Properties
Temperature
English
Chiral metal-organic frameworks (MOFs) have attracted a growing interest for their potential use in energy technologies, asymmetric catalysis, chiral separation, and on a more basic level, the creation of new topologies in inorganic materials. The current paper is the first report on a peptide-based MOF, a metal peptide framework (MPF), constructed from an oligovaline peptide family developed earlier by our group (Mantion, A.; et al. Macromol. Biosci. 2007, 7, 208). We have used a simple oligopeptide, Z-(L-Val)2-L-Glu(OH)-OH, to grow porous copper and calcium MPFs. The MPFs form thanks to the self-assembling properties of the peptide and specific metal-peptide and metal-ammonia interactions. They are stable up to ca. 250 degrees C and have some internal porosity, which makes them a promising prototype for the further development of MPFs.
- Language
-
- English
- Open access status
- closed
- Identifiers
-
- DOI 10.1021/ja0762588
- PMID 18247607
- Persistent URL
- https://folia.unifr.ch/global/documents/45707
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