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Mono-telechelic polymers by catalytic living ring-opening metathesis polymerization with second-generation Hoveyda–Grubbs catalyst

Université de Fribourg

  • Liu, Peng Department of Chemistry - University of Fribourg - 1700 Fribourg - Switzerland
  • Dong, Zhenghao Department of Chemistry - University of Fribourg - 1700 Fribourg - Switzerland
  • Kilbinger, Andreas F. M. Department of Chemistry - University of Fribourg - 1700 Fribourg - Switzerland
  • 27.08.2020
Published in:
  • Materials Chemistry Frontiers. - 2020, vol. 4, no. 9, p. 2791–2796
English The second-generation Hoveyda–Grubbs (HG2) catalyst, which has a small initiation to propagation rate ratio (ki/kp) in ring-opening metathesis polymerization (ROMP), was successfully used in a recently developed catalytic living ROMP. This proved that slow-initiating catalysts can enable ROMP in a living fashion to produce polymers with narrow dispersity and controlled molecular weight. The molecular weight control experiments show a linear relationship between polymer molecular weight and monomer to chain-transfer agent (CTA) ratio. Different norbornene-derivatives can be utilized as monomers. Di-block copolymers and tri-block copolymers can be synthesized either using the first polymer block as macro-CTA or continuously adding different monomers sequentially. Mono-telechelic polymers, with functional end groups such as protected carboxylic acid, alcohol and amine can also be achieved. All polymers were fully characterized using NMR, GPC and MALDI-ToF analytical techniques. This procedure provides access to well-defined end-functional polymers at lower cost and with reduced rare metal residues that might be of interest for biomedical, materials, industrial and academic use.
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
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Persistent URL
https://folia.unifr.ch/global/documents/309104
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