Journal article

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Catalytic living ring opening metathesis polymerisation: the importance of ring strain in chain transfer agents

Université de Fribourg

  • Liu, Peng Department of Chemistry, University of Fribourg, Switzerland
  • Yasir, Mohammad Department of Chemistry, University of Fribourg, Switzerland
  • Kilbinger, Andreas F. M. Department of Chemistry, University of Fribourg, Switzerland
    2019
Published in:
  • Angewandte Chemie International Edition. - 2019, vol. 58, no. 43, p. 15278–15282
English A recently developed catalytic living ring opening metathesis polymerisation (ROMP) was investigated using a series of reversible chain transfer agents (CTA) carrying either cyclopentene or cyclohexene rings, differing only in ring strain. All cyclopentene derivatives examined showed significantly faster reaction rates than the corresponding cyclohexene derivatives. This resulted in lower... Show more…
Faculty
Faculté des sciences et de médecine
Department
Département de Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/global/documents/308001
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