Transient anions of cis- and trans-cyclooctene studied by electron-impact spectroscopy
Université de Fribourg
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Regeta, Khrystyna
Department of Chemistry, University of Fribourg, Switzerland
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Nagarka, Amit
Department of Chemistry, University of Fribourg, Switzerland
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Kilbinger, Andreas F. M.
Department of Chemistry, University of Fribourg, Switzerland
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Allan, Michael
Department of Chemistry, University of Fribourg, Switzerland
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Published in:
- Physical Chemistry Chemical Physics. - 2015, vol. 17, no. 6, p. 4696–4700
English
The effect which deformation of the double bond in trans-cyclooctene (TCO), compared to cis-cyclooctene (CCO), has on its negative ion – and indirectly on the π* virtual orbital – was studied by electron-impact spectroscopy. Differential elastic and vibrational excitation cross sections were measured at a scattering angle of θ = 135°. The vertical attachment energy (VAE) derived from the... Show more…
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Faculty
- Faculté des sciences
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Department
- Chimie
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Language
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Classification
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Chemistry
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License
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License undefined
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Identifiers
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Persistent URL
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https://folia.unifr.ch/global/documents/304349