Journal article

Transient anions of cis- and trans-cyclooctene studied by electron-impact spectroscopy

Université de Fribourg

  • Regeta, Khrystyna Department of Chemistry, University of Fribourg, Switzerland
  • Nagarka, Amit Department of Chemistry, University of Fribourg, Switzerland
  • Kilbinger, Andreas F. M. Department of Chemistry, University of Fribourg, Switzerland
  • Allan, Michael Department of Chemistry, University of Fribourg, Switzerland
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    28.01.2015
Published in:
  • Physical Chemistry Chemical Physics. - 2015, vol. 17, no. 6, p. 4696–4700
English The effect which deformation of the double bond in trans-cyclooctene (TCO), compared to cis-cyclooctene (CCO), has on its negative ion – and indirectly on the π* virtual orbital – was studied by electron-impact spectroscopy. Differential elastic and vibrational excitation cross sections were measured at a scattering angle of θ = 135°. The vertical attachment energy (VAE) derived from the... Show more…
Faculty
Faculté des sciences
Department
Chimie
Language
  • English
Classification
Chemistry
License
License undefined
Identifiers
Persistent URL
https://folia.unifr.ch/global/documents/304349